双语化学辞典Chem Lexicon
初中Junior high 化学热力学 Chemical thermodynamics

热量计算Heat and heat capacity

\[Q = c\,m\,\Delta T = C\,\Delta T = nC_m\Delta T\]

含义Meaning

物体温度改变 ΔT 时吸收或放出的热量。比热容 c 是 1 kg(或 1 g)物质升温 1 K 所需热量;水的比热容很大,4.18 J/(g·K)。

Heat absorbed or released for a temperature change ΔT. Specific heat c is the heat to warm 1 kg (or 1 g) by 1 K; water’s is large, 4.18 J g⁻¹ K⁻¹.

符号说明Symbols

符号Symbol含义 Meaning单位 Unit
\(Q\)热量heatJ
\(c\)比热容specific heat capacityJ·g⁻¹·K⁻¹
\(C\)热容heat capacityJ·K⁻¹
\(C_m\)摩尔热容molar heat capacityJ·mol⁻¹·K⁻¹

推导Derivation

  1. 按定义 \(C = \delta Q/dT\);若 C 在温度范围内不变,积分得 \(Q = C\Delta T\)。

    By definition \(C = \delta Q/dT\); constant C integrates to \(Q = C\Delta T\).

  2. 热量计(量热法):反应放热被溶液和量热计吸收,\(q_\text{反应} = -(c\,m\,\Delta T + C_\text{cal}\Delta T)\)。

    Calorimetry: \(q_\text{rxn} = -(cm\Delta T + C_\text{cal}\Delta T)\).

适用条件与局限Assumptions & limitations

  • 不适用于有相变的过程(相变时吸热而温度不变);热容随温度变化时需积分。

    Not across phase changes; integrate if C varies with T.

  • 区分定压 Cp 与定容 Cv:气体两者差别大(\(C_p - C_V = R\))。

    Distinguish Cp and Cv (differ by R for ideal gases).

例题Worked example

把 200 g 水从 20 °C 加热到 100 °C:Q = 4.18×200×80 = 66.9 kJ。

Heating 200 g of water from 20 to 100 °C needs 66.9 kJ.