双语化学辞典Chem Lexicon
高中Senior high 原子结构与量子化起源 Atomic structure & the origins of quantisation

光电效应方程Photoelectric equation

\[E_{k,\max} = \tfrac12 m_ev_{\max}^2 = h\nu - \Phi,\qquad \nu_0 = \frac\Phi h\]

含义Meaning

光照射金属时,只有频率高于阈值 ν₀ 的光才能打出电子,与光强无关;光电子最大动能随频率线性增大。爱因斯坦(1905)用光子解释,获 1921 年诺贝尔物理学奖。

Light ejects electrons from a metal only above a threshold frequency ν₀, regardless of intensity; the maximum kinetic energy rises linearly with frequency. Einstein’s photon explanation (1905) won the 1921 Nobel Prize in Physics.

符号说明Symbols

符号Symbol含义 Meaning单位 Unit
\(\Phi\)逸出功(功函数)work functioneV
\(\nu_0\)截止频率threshold frequencyHz
\(E_{k,\max}\)光电子最大动能maximum photoelectron kinetic energyeV

推导Derivation

  1. 一个光子把全部能量 hν 交给一个电子。

    One photon gives all its energy hν to one electron.

  2. 电子逸出至少消耗 Φ,剩余为动能。

    Escape costs at least Φ; the rest is kinetic energy.

  3. 用遏止电压测量:\(eU_s = h\nu - \Phi\);直线斜率 h/e(密立根 1916 年据此测得 h)。

    Stopping voltage: \(eU_s = h\nu - \Phi\); the slope h/e gave Millikan’s 1916 value of h.

适用条件与局限Assumptions & limitations

  • 表面状况影响 Φ;温度效应和多光子过程略去。

    Surface condition affects Φ; thermal and multiphoton effects ignored.

例题Worked example

钠 Φ = 2.28 eV(ν₀ = 5.5×10¹⁴ Hz,λ₀ = 544 nm);用 400 nm 光照射时 E_k,max = 3.10 − 2.28 = 0.82 eV。

Sodium Φ = 2.28 eV; 400 nm light gives E_k,max = 0.82 eV.