双语化学辞典Chem Lexicon
本科Undergraduate 表面、胶体与传递过程 Surfaces, colloids & transport

斯托克斯定律与沉降速度Stokes' law and sedimentation velocity

\[F_d = 6\pi\eta rv,\qquad v_t = \frac{2r^2(\rho_p - \rho_f)g}{9\eta}\]

含义Meaning

小球在黏性流体中低速运动时所受阻力与速度成正比(1851)。重力、浮力与阻力平衡时达到终端沉降速度,与半径平方成正比——用于粒度分析、离心分离、密立根油滴实验。

At low speed a sphere’s drag is proportional to velocity (1851). Balancing gravity, buoyancy and drag gives a terminal velocity ∝ r² — used in particle sizing, centrifugation and Millikan’s oil-drop experiment.

符号说明Symbols

符号Symbol含义 Meaning单位 Unit
\(F_d\)黏性阻力viscous dragN
\(v_t\)终端速度terminal velocitym·s⁻¹
\(\rho_p, \rho_f\)颗粒、流体密度particle and fluid densitieskg·m⁻³

推导Derivation

  1. 求解低雷诺数(\(Re = \rho vr/\eta \ll 1\))纳维–斯托克斯方程,得球的阻力 \(6\pi\eta rv\)。

    Solving low-Re Navier–Stokes gives drag \(6\pi\eta rv\).

  2. 终端时 \(\tfrac43\pi r^3(\rho_p - \rho_f)g = 6\pi\eta rv\),解出 \(v_t\)。

    Balance net weight with drag.

  3. 离心场中把 g 换成 \(\omega^2r_\text{rot}\)。

    In a centrifuge replace g by ω²r.

适用条件与局限Assumptions & limitations

  • 只适用于 Re < 约 0.1–1 的球形颗粒;颗粒浓度高时相互干扰(受阻沉降);极小颗粒还受布朗运动影响。

    Valid for spheres at Re < ~0.1–1; concentrated suspensions hinder settling; tiny particles are dominated by Brownian motion.

例题Worked example

半径 1 μm 的石英颗粒(ρ = 2650 kg/m³)在水中:v = 2×10⁻¹²×1650×9.81/(9×8.9×10⁻⁴) = 4.0 μm/s,沉降 10 cm 约需 7 小时。

A 1 μm quartz grain settles at 4 μm/s in water — ~7 h for 10 cm.