定义Definition
化学式用元素符号和数字表示物质的组成。分子化合物用分子式表示每个分子中各原子的实际数目(如 C₆H₁₂O₆);离子化合物用最简整数比表示(如 NaCl、CaCl₂),称为式单位;实验式只给出最简原子数比(如葡萄糖为 CH₂O)。
A chemical formula shows the composition of a substance with element symbols and numbers. A molecular formula gives the actual number of each atom in a molecule (C₆H₁₂O₆); an ionic compound is written in its simplest whole-number ratio (NaCl, CaCl₂), called a formula unit; an empirical formula gives only the simplest ratio (CH₂O for glucose).
离子化合物的写法Writing ionic formulae
使正负电荷总数相等:Al³⁺ 与 O²⁻ 组成 Al₂O₃;Ca²⁺ 与 NO₃⁻ 组成 Ca(NO₃)₂,多原子离子多于一个时加括号。
Balance the charges: Al³⁺ and O²⁻ give Al₂O₃; Ca²⁺ and NO₃⁻ give Ca(NO₃)₂, with brackets round a polyatomic ion that appears more than once.
几种化学式的比较Kinds of formula
以乙酸为例:分子式 C₂H₄O₂;实验式 CH₂O;结构简式 CH₃COOH;展开式和键线式还能显示原子的连接方式。结晶水写在点后,如 CuSO₄·5H₂O。
For ethanoic acid: molecular formula C₂H₄O₂; empirical formula CH₂O; structural formula CH₃COOH; displayed and skeletal formulae also show how the atoms are joined. Water of crystallisation follows a dot, as in CuSO₄·5H₂O.
年表Timeline
- 1813
贝采利乌斯提出用字母表示元素的化学符号体系
Berzelius proposes letter symbols for the elements