双语化学辞典Chem Lexicon
反应 · 核化学 · 核反应 Nuclear chemistry · Nuclear reactions

链式反应(核)Nuclear chain reaction

拼音Pinyin liàn shì fǎn yìng 别名Also 核链式反应;裂变链式反应; fission chain reaction

定义Definition

核链式反应是指重核裂变放出的中子又引起其他重核裂变、使裂变反应自行持续下去的过程。控制每代中子数的增长,可使反应在反应堆中稳定运行,或在核武器中瞬间释放巨大能量。

A nuclear chain reaction is the self-sustaining process in which neutrons released by fission cause further fissions. Controlling how the neutron population grows from one generation to the next lets a reactor run steadily or a weapon release enormous energy in an instant.

原理Principle

有效增殖因数 k 定义为一代中子引起的下一代中子数之比。k < 1 为次临界,反应逐渐熄灭;k = 1 为临界,反应稳定持续;k > 1 为超临界,中子数指数增长。反应堆中约 0.65% 的缓发中子(来自裂变产物的衰变,延迟数秒)使功率变化足够缓慢,控制棒(含硼、镉)有时间调节,这是反应堆可控的关键。

The effective multiplication factor k is the ratio of neutrons in one generation to the previous one. If k < 1 the system is subcritical and the reaction dies away; k = 1 is critical and steady; k > 1 is supercritical, with exponential growth. In a reactor about 0.65% of neutrons are delayed by seconds because they come from decaying fission products, which slows power changes enough for boron or cadmium control rods to respond; this is what makes reactors controllable.

由来Origin

1933 年西拉德在伦敦过马路时想到:如果某种核反应吸收一个中子能放出两个,就可能形成链式反应,并于 1934 年申请专利。1939 年发现铀裂变每次放出 2–3 个中子后,这一设想成为现实。1942 年 12 月 2 日,费米领导的团队在芝加哥大学建成芝加哥一号堆,首次实现人工可控链式反应。

In 1933, crossing a London street, Leo Szilard realised that a nuclear reaction absorbing one neutron and emitting two could sustain a chain, and he filed a patent in 1934. Once uranium fission was found in 1939 to release two or three neutrons, the idea became real. On 2 December 1942 Fermi's team at the University of Chicago started Chicago Pile-1, the first man-made controlled chain reaction.

反应堆中的控制Control in reactors

热中子堆用水、重水或石墨作慢化剂,把快中子减速为热中子以提高 ²³⁵U 的裂变截面。水在压水堆中既是慢化剂又是冷却剂,具有负温度反馈:温度升高时水密度降低,慢化减弱,k 下降。切尔诺贝利 RBMK 堆采用石墨慢化,存在正空泡系数,是 1986 年事故的重要原因之一。

Thermal reactors use water, heavy water or graphite as a moderator to slow fast neutrons and raise the fission cross-section of ²³⁵U. In a pressurised water reactor water is both moderator and coolant and gives negative temperature feedback: hotter water is less dense, moderates less and lowers k. Chernobyl's graphite-moderated RBMK had a positive void coefficient, a major factor in the 1986 accident.

反应Reactions

1 n + 235U ⟶ 裂变碎片 + 2.4 n平均 ⟶ 引发下一代裂变1 n + 235U ⟶ Nuclear fission + 2.4 n ⟶ Nuclear fission

k = 1 时功率恒定。

Power is constant when k = 1.

中子数 Nₙ = N0·kⁿn 为代数Neutron Nₙ = N0·kⁿ(n )

中子数按代增长

Neutron numbers grow by generation

10B + n ⟶ 7Li + 4He

硼控制棒吸收中子

Boron control rods absorb neutrons

年表Timeline

  • 1933

    西拉德构想核链式反应

    Szilard conceives the nuclear chain reaction

  • 1939

    测得每次裂变放出 2–3 个中子

    Fission is found to release two or three neutrons

  • 1942

    芝加哥一号堆达到临界

    Chicago Pile-1 goes critical

  • 1972

    发现加蓬奥克洛约 20 亿年前的天然核反应堆

    The two-billion-year-old natural reactor at Oklo, Gabon, is discovered