双语化学辞典Chem Lexicon
本科Undergraduate 放射性衰变与核结构 Radioactive decay & nuclear structure

放射性活度Radioactivity (activity)

\[A = -\frac{dN}{dt} = \lambda N = \frac{\ln2}{t_{1/2}}\cdot\frac{m N_A}{M},\qquad A(t) = A_0e^{-\lambda t}\]

含义Meaning

单位时间的衰变数,SI 单位贝克勒尔(1 Bq = 1 次衰变/秒),旧单位居里(1 Ci = 3.7×10¹⁰ Bq,约等于 1 g ²²⁶Ra 的活度)。

Decays per unit time; SI unit becquerel (1 Bq = 1 s⁻¹); the curie (1 Ci = 3.7×10¹⁰ Bq) is roughly 1 g of ²²⁶Ra.

符号说明Symbols

符号Symbol含义 Meaning单位 Unit
\(A\)活度activityBq
\(m\)核素质量mass of nuclideg
\(M\)摩尔质量molar massg·mol⁻¹

推导Derivation

  1. 活度即衰变速率 \(\lambda N\);N 由质量换算 \(N = mN_A/M\)。

    Activity is λN with \(N = mN_A/M\).

  2. 比活度 \(A/m = \lambda N_A/M\):半衰期越短、质量数越小,比活度越高。

    Specific activity λN_A/M is higher for short-lived, light nuclides.

适用条件与局限Assumptions & limitations

  • 活度不等于剂量:生物效应还取决于辐射类型、能量、吸收方式(Gy、Sv)。

    Activity is not dose; biological effect depends on radiation type and energy (Gy, Sv).

例题Worked example

1 g ²²⁶Ra(t½ = 1600 a):A = 0.693/(1600×3.156×10⁷ s) × 6.022×10²³/226 = 3.66×10¹⁰ Bq ≈ 1 Ci。

1 g ²²⁶Ra: A ≈ 3.66×10¹⁰ Bq ≈ 1 Ci.