双语化学辞典Chem Lexicon
本科Undergraduate 溶液与依数性 Solutions & colligative properties

质量摩尔浓度Molality

\[b_\mathrm{B} = \frac{n_\mathrm{B}}{m_\mathrm{A}}\]
与物质的量浓度换算(ρ 用 g/mL)conversion from molarity (ρ in g/mL)
\[b = \frac{1000\,c}{1000\rho - cM_\mathrm{B}}\]

含义Meaning

每千克溶剂中溶质的物质的量,单位 mol/kg。不随温度变化,是依数性公式所用的浓度。

Amount of solute per kilogram of solvent (mol/kg). Temperature-independent; used in colligative-property formulas.

符号说明Symbols

符号Symbol含义 Meaning单位 Unit
\(b_\mathrm{B}\)溶质 B 的质量摩尔浓度molality of Bmol·kg⁻¹
\(m_\mathrm{A}\)溶剂质量mass of solventkg

推导Derivation

  1. 按定义;分母是溶剂而非溶液的质量。

    By definition; the denominator is the solvent mass, not the solution’s.

  2. 1 L 溶液质量 \(1000\rho\) g,含溶质 \(c\) mol 即 \(cM_\mathrm{B}\) g,溶剂质量 \((1000\rho - cM_\mathrm{B})\) g,得换算式。

    1 L of solution weighs \(1000\rho\) g, of which \(cM_\mathrm{B}\) g is solute; the rest is solvent.

适用条件与局限Assumptions & limitations

  • 稀水溶液中 \(b \approx c\)(数值上,mol/kg ≈ mol/L)。

    In dilute aqueous solution \(b \approx c\) numerically.