双语化学辞典Chem Lexicon
点群 Point group

S4 点群特征标表S4 character table

国际符号(Hermann–Mauguin)Hermann–Mauguin symbol 4̄
S4ES4C2S4³线性 / 转动linear, rotations二次quadratic
A1111Rzx²+y², z²
B1−11−1zx²−y², xy
E12i0−1−2−i0(x, y), (Rx, Ry)(xz, yz)
↳ 共轭conj.1−i−1i

\(\varepsilon = \exp(2\pi i/4)\),\(\varepsilon^{*}\) 为其复共轭。合并后每对复共轭不可约表示相加成一个二维实表示(物理上简并)。; \(\varepsilon^{*}\) is its complex conjugate. Merging adds each conjugate pair into one two-dimensional real representation (physically degenerate).

阶 hOrder h4
类数Classes4
所属族FamilySn
代表分子Examples四苯基甲烷(某些构象), 1,3,5,7-四甲基环辛四烯tetraphenylmethane (some conformers), 1,3,5,7-tetramethylcyclooctatetraene

约化可约表示Reduce a representation

输入可约表示在各类上的特征标,按约化公式 \(n_i = \frac{1}{h}\sum_R g_R\,\chi(R)\,\chi_i(R)^{*}\) 求出各不可约表示出现的次数。

Enter the characters of a reducible representation; the reduction formula gives how many times each irreducible representation occurs.