定义Definition
容量瓶是一种细颈梨形平底、带磨口塞、颈上有一条标线的玻璃量器,用于准确配制一定体积、一定浓度的溶液。常见规格有 10、25、50、100、250、500、1000 mL。
A volumetric flask is a pear-shaped, flat-bottomed glass flask with a narrow neck bearing a single mark and a ground stopper, used to prepare solutions of accurately known volume and concentration. Common sizes are 10, 25, 50, 100, 250, 500 and 1000 mL.
使用方法How to use it
配制溶液步骤:计算 → 称量(或量取)→ 在烧杯中溶解并冷却至室温 → 用玻璃棒引流转移入容量瓶 → 用少量溶剂洗涤烧杯和玻璃棒 2–3 次,洗液一并转入 → 加溶剂至距标线 1–2 cm 处 → 改用胶头滴管滴加至弯月面最低点与标线相切 → 盖塞,反复倒转摇匀。
To make a solution: calculate → weigh or measure → dissolve in a beaker and cool to room temperature → transfer down a glass rod into the flask → rinse beaker and rod two or three times with a little solvent and add the rinsings → add solvent to 1–2 cm below the mark → finish dropwise with a dropper until the bottom of the meniscus meets the mark → stopper and invert repeatedly to mix.
注意事项Cautions
容量瓶是“量入式”量器,刻度在 20 °C 校准,不能加热、不能在其中溶解固体或进行反应(溶解热会改变体积),不能长期储存溶液(尤其是碱液,会腐蚀玻璃使瓶塞粘住)。使用前须检查瓶塞是否漏水。定容时若超过标线,只能重新配制。
Volumetric flasks are calibrated to contain at 20 °C; never heat them, dissolve solids or run reactions in them (heats of solution change the volume), or store solutions in them long-term, especially alkalis, which etch the glass and seize the stopper. Check the stopper for leaks before use, and if you overshoot the mark, start again.
精度Accuracy
A 级 100 mL 容量瓶允差 ±0.10 mL,250 mL 为 ±0.15 mL。分析化学中常用容量瓶配制标准溶液和进行准确稀释,配合移液管使用。
A class-A 100 mL flask is accurate to ±0.10 mL and a 250 mL flask to ±0.15 mL. In analytical chemistry volumetric flasks are used with pipettes to prepare standard solutions and make accurate dilutions.
年表Timeline
- 19 世纪
容量分析发展,容量瓶标准化
Volumetric analysis develops and volumetric flasks are standardised
相关公式Formulas
例题Worked example
把 5.85 g NaCl 溶于水配成 250 mL 溶液:n = 0.100 mol,c = 0.100/0.250 = 0.400 mol/L。
5.85 g NaCl made up to 250 mL: n = 0.100 mol, c = 0.400 mol/L.