双语化学辞典Chem Lexicon
研究生Graduate 量子力学基础与模型体系 Quantum mechanics & model systems

量子隧穿(矩形势垒)Quantum tunnelling through a rectangular barrier

\[T \approx 16\frac{E}{V_0}\left(1 - \frac{E}{V_0}\right)e^{-2\kappa a},\qquad \kappa = \frac{\sqrt{2m(V_0 - E)}}{\hbar}\]

含义Meaning

能量低于势垒的粒子仍有一定概率穿过势垒。透射率随势垒宽度 a 和 \(\sqrt{m}\) 指数衰减,所以电子、质子隧穿显著,重原子几乎不隧穿。

A particle with E < V₀ can still pass a barrier. Transmission decays exponentially with width and √m, so electrons and protons tunnel appreciably while heavy atoms hardly do.

符号说明Symbols

符号Symbol含义 Meaning单位 Unit
\(T\)透射系数transmission coefficient1
\(V_0\)势垒高度barrier heightJ
\(a\)势垒宽度barrier widthm
\(\kappa\)衰减常数decay constantm⁻¹

推导Derivation

  1. 势垒内 \(E < V_0\),方程解为 \(Ce^{\kappa x} + De^{-\kappa x}\)(指数而非振荡)。

    Inside the barrier the solutions are exponentials \(e^{\pm\kappa x}\).

  2. 三个区域在 x = 0、a 处 ψ 与 ψ′ 连续,求出透射振幅。

    Match ψ and ψ′ at both edges to obtain the transmitted amplitude.

  3. 厚势垒(\(\kappa a \gg 1\))时主导项为 \(e^{-2\kappa a}\),得到近似式。

    For thick barriers the \(e^{-2\kappa a}\) term dominates.

适用条件与局限Assumptions & limitations

  • 矩形势垒是理想化;真实反应势垒用 WKB 近似 \(T \approx \exp(-2\int\kappa(x)dx)\) 或 Wigner/Bell 校正。

    Rectangular barriers are idealised; use WKB or Wigner/Bell corrections for real barriers.

例题Worked example

扫描隧道显微镜:隧道电流随针尖–样品距离每增加 1 Å 下降约一个数量级。

STM current falls about tenfold per ångström of tip–sample separation.