定义Definition
圆底烧瓶是一种球形瓶身、带一个或多个磨口瓶颈的玻璃容器,受热均匀、耐压,是有机合成中进行加热反应、回流和蒸馏的主要容器。
A round-bottom flask is a spherical glass vessel with one or more ground-glass necks. It heats evenly and withstands pressure differences, and is the main vessel for heated reactions, reflux and distillation in organic synthesis.
特点Features
球形结构使应力均匀分布,能承受减压和加热时的内外压差,比平底瓶更不易破裂;受热均匀,适合加热套、油浴、水浴加热和磁力搅拌。不能平放,需用软木圈、烧瓶托架或铁夹固定。标准磨口(如 14/23、19/26、24/29,数字为磨口大端直径/磨口长度 mm)使各种仪器可以互相连接组装。
The sphere spreads stress evenly, so it withstands vacuum and heating better than a flat-bottomed flask; it heats uniformly and suits heating mantles, oil and water baths and magnetic stirring. It cannot stand on its own and is held in a cork ring, stand or clamp. Standard-taper joints such as 14/23, 19/26 and 24/29 (wide-end diameter/ground length in mm) let apparatus be assembled interchangeably.
类型Types
单口烧瓶用于一般反应和蒸馏;两口、三口、四口烧瓶可同时安装冷凝管、温度计、滴液漏斗、搅拌器和气体导管;梨形烧瓶(茄形瓶)底部尖,适合少量液体和旋转蒸发;施兰克瓶带侧管活塞,用于无水无氧操作。
Single-necked flasks serve general reactions and distillation; two-, three- and four-necked flasks take a condenser, thermometer, dropping funnel, stirrer and gas inlet at once; pear-shaped flasks with pointed bottoms suit small volumes and rotary evaporation; and Schlenk flasks with a side-arm stopcock are used for air- and moisture-free work.
安全Safety
使用前检查有无裂纹和星裂,特别是减压操作时;液体量一般为容积的 1/3 到 2/3;加热前加沸石或搅拌子;磨口处可涂少量真空脂以防粘结,但会污染产物,聚四氟乙烯套更清洁。
Check for cracks and star cracks before use, especially under vacuum; fill to between a third and two-thirds; add boiling chips or a stir bar before heating; a little vacuum grease prevents joints seizing but can contaminate products, and PTFE sleeves are cleaner.
年表Timeline
- 1920s
标准磨口玻璃仪器推广
Standard-taper ground-glass joints spread